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Polyaromatic polymerization inhibitor, Quino Power™

The Quino Power™ series consists of polyaromatic polymerization inhibitors with a polyaromatic structure. This is a functional polymerization inhibitor with the following unique features that are not seen with conventional monoaromatic compounds like HQ (hydroquinone), MQ (4-methoxyphenol), and TBC (t-butylcatechol), or transition metal salts.

Features

  1. Excellent inhibition property under non-oxygen conditions
  2. Monophilic:
    Oil-soluble/water-insoluble (easily soluble in hydrophobic organic solvent and insoluble in water)
    (Conventional monoaromatic polymerization inhibitors such as HQ, MQ, and TBC are amphipathic)
    (Tables 2)
  3. Excellent heat resistance (high boiling temperature and lower volatility)
    It has higher boiling temperature and lower volatility than monoaromatic polymerization inhibitors. Especially ATR has a lower volatility.
  4. Metal-free: No alkaline metals/transition metals are contained.
  5. Halogen free: No halogen elements are contained.
Properties/applications of Quino Power™ (Table 1)
Product name Quino Power™
MNT
Quino Power™
NQI
Quino Power™
LSN
Quino Power™
ATR
Structure
Molecular weight 174.2 158.2 174.2 194.2
Water-solubility
Oil-solubility
Feature/
application
Suitable for acrylate Suitable for styrene, methyl methacrylate(MMA) and unsaturated polyester Suitable for vinyl acetate (having low oxidation-reduction potential) Application for high boiling temperatures
Boiling point 320℃
(MQ: 243℃)

Monophlic property of Quino Power™

Solubility of oil-soluble Quino Power™ (Table 2)
  Oil solubility
(g/100g,25℃)
Water solubility
(g/100g,25℃)
Remarks
(solvent)
MNT 10 0.1 Toluene
NQI 10 0.01 o-xylene
LSN 7.5 0.1 Methyl cellosolve
ATR 6 0.01 o-xylene
HQ(hydroquinone) (for comparison) 10 5.8 Toluene
MQ(4-methoxyphenol) (for comparison) 69.5 4.1 Benzene
TBC(t-butylcatechol) (for comparison) 30 85 Toluene

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